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11-Hydroxyundecyl octadecyl disulfide self-assembled monolayers on Au(1 1 1)     
Yazarlar (4)
Dr. Öğr. Üyesi Erol ALBAYRAK Dr. Öğr. Üyesi Erol ALBAYRAK
Kırşehir Ahi Evran Üniversitesi, Türkiye
Semistan Karabuga
Kahramanmaras Sütçü Imam Üniversitesi, Türkiye
Gianangelo Bracco
Università Degli Studi Di Genova, İtalya
M. Fatih Danişman
Middle East Technical University (Metu), Türkiye
Devamını Göster
Özet
Here, we report a helium atom diffraction study of 11-hydroxyundecyl octadecyl disulfide (CH 3 (CH 2 ) 17 SS(CH 2 ) 11 OH, HOD) self-assembled monolayers (SAMs) produced by supersonic molecular beam deposition (SMBD). Two different lying down monolayer phases were observed depending on the substrate temperature. At low temperatures a poorly ordered phase was observed, while the diffraction patterns of the film grown at high temperatures were similar to that of mercaptoundecanol (MUD) SAMs reported previously in the literature. The transition from the low temperature phase to the high temperature phase is due to SS bond cleavage at the surface. Desorption from several different chemisorbed and physisorbed states were observed with energies in the same range as observed for MUD and octadecanelthiol (ODT) SAMs. © 2014 Elsevier B.V.
Anahtar Kelimeler
Au(1 1 1) | Helium diffraction | Low energy atom scattering | Self-assembled monolayers | Supersonic molecular beam deposition | Unsymmetric disulfides
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Applied Surface Science
Dergi ISSN 0169-4332 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili İngilizce
Basım Tarihi 08-2014
Cilt No 311
Sayı 1
Sayfalar 643 / 647
Doi Numarası 10.1016/j.apsusc.2014.05.128
Makale Linki http://dx.doi.org/10.1016/j.apsusc.2014.05.128