Yazarlar (4) |
![]() Ahi Evran Üniversitesi, Türkiye |
![]() Kahramanmaraş Sütçü İmam Üniversitesi, Türkiye |
![]() |
![]() Orta Doğu Teknik Üniversitesi, Türkiye |
Özet |
We have investigated the formation of self-assembled monolayers (SAMs) of 11-hydroxyundecyl decyl disulfide (CH 3 -(CH 2 ) 9 -S-S-(CH 2 ) 11 -OH, HDD) and 11-hydroxyundecyl octadecyl disulfide (CH 3 -(CH 2 ) 17 -S-S-(CH 2 ) 11 -OH, HOD) produced by supersonic molecular beam deposition (SMBD). The study has been carried out by means of helium diffraction at very low film coverage. In this regime helium single molecule cross sections have been estimated in a temperature range between 100 K and 450 K. The results show a different behavior above 300 K that has been interpreted as the starting of mobility with the formation of two thiolate moieties either linked by a gold adatom or distant enough to prevent cross section overlapping. Finally, helium diffraction patterns measured at 80 K for the SAMs grown at 200 K are discussed and the results support the proposed hypothesis of molecular dissociation based on the cross section data. |
Anahtar Kelimeler |
11-Hydroxyundecyl decyl disulfide | 11-Hydroxyundecyl octadecyl disulfide | Self-assembled monolayers | Supersonic molecular beam deposition | The scattering cross sections | Unsymmetric disulfides |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | Applied Surface Science |
Dergi ISSN | 0169-4332 Wos Dergi Scopus Dergi |
Dergi Tarandığı Indeksler | SCI-Expanded |
Dergi Grubu | Q1 |
Makale Dili | İngilizce |
Basım Tarihi | 12-2016 |
Cilt No | 390 |
Sayı | 1 |
Sayfalar | 283 / 288 |
Doi Numarası | 10.1016/j.apsusc.2016.08.062 |
Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0169433216317044 |