A new synthesis of limonene copolymer: experimental and theoretical analysis
    
Yazarlar (4)
Nevin Cankaya
Usak University, Türkiye
Prof. Dr. Emine TANIŞ Kırşehir Ahi Evran Üniversitesi, Türkiye
H. Elmalı Gülbaş
Usak University, Türkiye
Niyazi Bulut
Firat Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polymer Bulletin
Dergi ISSN 0170-0839 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 09-2018
Cilt / Sayı / Sayfa 76 / 7 / 3297–3327 DOI 10.1007/s00289-018-2543-3
Makale Linki http://link.springer.com/10.1007/s00289-018-2543-3
Özet
A copolymer of limonene with 2-(4-methoxyphenylamino)-2-oxoethyl methacrylate (LIM-co-MPAEMA) which is thought to be a non-toxic and used generally as a dietary supplement was synthesized and characterized for the first time both experimentally and theoretically. The structure of synthesized limonene copolymer was chemically characterized by Fourier transform infrared and nuclear magnetic resonant (1H NMR) spectroscopic techniques and compared with the theoretical calculated results. Charge transfer that is important in the formation of chemically bonded adducts causing cancer is quantitatively calculated. It was found that this polymer can be used as a biomaterial.
Anahtar Kelimeler
2-(4-Methoxyphenylamino)-2-oxoethyl methacrylate (MPAEMA) | Density functional theory (DFT) | LIM-co-MPAEMA | Limonene