New Syntheses of 4NPMA Homopolymer and Its Copolymer with Limonene: Experimental Analysis and Density Functional Theory Study
Yazarlar (3)
Nevin Çankaya Uşak Üniversitesi, Türkiye
Prof. Dr. Emine TANIŞ Kırşehir Ahi Evran Üniversitesi, Türkiye
Pembe Gül Sapan Usak University
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Russian Journal of Physical Chemistry A (Q3) | ||
| Dergi ISSN | 1531-863X Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Kabul Tarihi | 12-04-2026 | Yayınlanma Tarihi | – |
| Cilt / Sayı / Sayfa | 95 / 1 / 139–153 | DOI | 10.1134/S0036024421010052 |
| Makale Linki | https://www.springer.com/journal/11504 | ||
| Özet |
| The N-(4-nitrophenyl)methacrylamide homopolymer (poly(4NPMA)) and copolymer of limonene with N-(4-nitrophenyl)methacrylamide (4NPMA-co-LIM) have been synthesized and characterized by FT-IR and NMR spectroscopic methods. The spectroscopic properties of poly(4NPMA) and 4NPMA-co-LIM were predicted using Density Functional Theory (DFT) calculations. The results have been compared with observed values, and they match with each other. Frontier orbital analysis (FMOs), global reactivity descriptors, MEP as well as Mulliken atomic charge were calculated with same method for poly(4NPMA) and 4NPMA-co-LIM. The physical properties of homopolymer of NPMA and its copolymer with D-Limonene were compared and evaluated. Thermal stabilities of homo and copolymer were investigated. |
| Anahtar Kelimeler |
| 4NPMA-co-LIM | density functional theory (DFT) | frontier orbital analysis | MEP | poly(4NPMA) |
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| Atıf Sayıları | |
| Google Scholar | 2 |
| Scopus | 1 |
| Web of Science | 1 |