| Yazarlar (5) |
Kenan Buldurun
Muş Alparslan Üniversitesi, Türkiye |
Prof. Dr. Emine TANIŞ
Kırşehir Ahi Evran Üniversitesi, Türkiye |
|
Nevin Turan Özek
Muş Alparslan Üniversitesi, Türkiye |
|
Naki Çolak
Hitit Üniversitesi, Türkiye |
|
Nevin Çankaya
Uşak Üniversitesi, Türkiye |
| Özet |
| In this article, the electronic, optical, and charge transfer properties of a Schiff base ligand prepared using 5-bromo-2-hydroxybenzaldehyde and ethyl 6-acetyl-2-amino-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate (C19H19BrN2O4S) and its Fe(II) (C19H30BrN2O10SClFe), Ni(II) (C19H28BrN2O9SClNi), and Zn(II) (C19H28BrN2O9SClZn) complexes are described based on different solvents environments and supported by theoretical calculations. Theoretical calculations are carried out using density functional theory (DFT/UB3LYP/LANL2DZ). The optical densities, optical band gaps, and refractive indices of the ligand and its Fe(II), Ni(II), and Zn(II) complexes in different solvent environments are obtained. The reorganization energies are calculated to determine the charge transfer rate of the studied compounds using both experimental and theoretical data. These experimental and theoretical results show that the ligand and its metal complexes can be used for optoelectronic applications and charge transfer materials in organic light-emitting diode applications. |
| Anahtar Kelimeler |
| charge transfer properties | metal complexes | nonlinear optical properties | optical parameters | Schiff base |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | Journal of Chemical Research |
| Dergi ISSN | 1747-5198 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | Türkçe |
| Basım Tarihi | 01-2021 |
| Cilt No | 45 |
| Sayı | 7 |
| Sayfalar | 753 / 759 |
| Doi Numarası | 10.1177/1747519821995424 |
| Makale Linki | http://dx.doi.org/10.1177/1747519821995424 |
| Atıf Sayıları | |
| WoS | 8 |
| SCOPUS | 9 |
| Google Scholar | 8 |
