| Yazarlar |
Harun ÇİFTÇİ
Ahi Evran Üniversitesi, Türkiye |
Dr. Öğr. Üyesi Çiğdem ER ÇALIŞKAN
Ahi Evran Üniversitesi, Türkiye |
| Özet |
| In the present study, a separation/preconcentration procedure for determination of aluminum in water samples has been developed by using a new atomic absorption spectrometer concept with a high-intensity xenon short-arc lamp as continuum radiation source, a high-resolution double-echelle monochromator, and a charge-coupled device array detector. Sample solution pH, sample volume, flow rate of sample solution, volume, and concentration of eluent for solid-phase extraction of Al chelates with 4-[(dicyanomethyl)diazenyl] benzoic acid on polymeric resin (Duolite XAD-761) have been investigated. The adsorbed aluminum on resin was eluted with 5 mL of 2 mol L-1 HNO3 and its concentration was determined by high-resolution continuum source flame atomic absorption spectrometry (HR-CS FAAS). Under the optimal conditions, limit of detection obtained with HR-CS FAAS and Line Source FAAS (LS-FAAS) were 0.49 mu g L-1 and 3.91 mu g L-1, respectively. The accuracy of the procedure was confirmed by analyzing certified materials (NIST SRM 1643e, Trace elements in water) and spiked real samples. The developed procedure was successfully applied to water samples. |
| Anahtar Kelimeler |
| Preconcentration, Tracemetal, Aluminum, Separation |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | ENVIRONMENTAL MONITORING AND ASSESSMENT (Springer Science and Business Media) LLC |
| Dergi ISSN | 0167-6369 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q2 |
| Makale Dili | İngilizce |
| Basım Tarihi | 06-2012 |
| Cilt No | 185 |
| Sayı | 3 |
| Sayfalar | 2745 / 2753 |
| Doi Numarası | 10.1007/s10661-012-2745-3 |
| Makale Linki | http://dx.doi.org/10.1007/s10661-012-2745-3 |
| Atıf Sayıları | |
| Google Scholar | 32 |
