Structural phase transition and electronic properties of CaO under high pressure
Yazarlar (3)
Prof. Dr. Cihan KÜRKÇÜ Kırşehir Ahi Evran Üniversitesi, Türkiye
Ziya Merdan Gazi Üniversitesi, Türkiye
Doç. Dr. Çağatay Yamçıçıer Gazi Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Materials Research Express (Q3) | ||
| Dergi ISSN | 2053-1591 Dergi Bilgileri (2018) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2018 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 28-09-2018 |
| Cilt / Sayı / Sayfa | 5 / 12 / 125903–0 | DOI | 10.1088/2053-1591/aae012 |
| Makale Linki | http://stacks.iop.org/2053-1591/5/i=12/a=125903?key=crossref.8a66a54af3ff6ed54f7f2d7cd16784a2 | ||
| UAK Araştırma Alanları |
Yoğun Madde Fiziği
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| Özet |
| The crystal structure of the CaO compound is studied up to 300 GPa under high hydrostatic pressure using the density functional theory (DFT) with the generalized gradient approximation (GGA). Pressure-volume relationships, structural transitions and electronic properties in CaO compound are investigated using Siesta method. CaO crystallizes in the NaCl-type (B1) structure (space group: Fm 3 ¯ m ) in ambient conditions. CaO transforms from this structure to CsCl-type (B2) structure (space group: Pm 3 ¯ m ) at high pressure. This transformation is based on a intermediate state with space group R 3 ¯ m . Moreover, the electronic band structures of the B1 and B2 structures of CaO have been calculated. According to this calculation, obtained band gap values are in good agreement with the values reported in the literature. |
| Anahtar Kelimeler |
| CaO | intermediate state | molecular dynamics | phase transition |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 13 |
| Scopus | 12 |
| Google Scholar | 17 |