A simplified molecular imprinting strategy through electrospinning of polyacrylonitrile for thin film microextraction of selected pesticides
 
Yazarlar (5)
Dr. Öğr. Üyesi Alper Şahin Middle East Technical University (Metu), Türkiye
Dr. Öğr. Üyesi Yeliz AKPINAR Kırşehir Ahi Evran Üniversitesi, Türkiye
Erol Yildirim Middle East Technical University (Metu), Türkiye
Ahmet E. Eroğlu Izmir Yüksek Teknoloji Enstitüsü, Türkiye
Ezel Boyaci Middle East Technical University (Metu), Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Chromatography A (Q1)
Dergi ISSN 0021-9673 Dergi Bilgileri (2026)
Dergi Tarandığı Indeksler SCI
Makale Dili Türkçe Basım Tarihi 01-2026
Cilt / Sayı / Sayfa 1767 / 1 / 466660–0 DOI 10.1016/j.chroma.2025.466660
Makale Linki https://www.sciencedirect.com/science/article/pii/S0021967325010040
UAK Araştırma Alanları
Nanoteknoloji Analitik Kimya Yeşil Kimya
Özet
Molecularly imprinted polymers (MIPs) have been extensively used as selective extractive phases for sample preparation because of their analyte-selective binding sites. However, MIP preparation requires optimized monomer-template interactions and long polymerization reactions.In this study, a novel and simple method of MIP preparation was proposed based on electrospinning. Instead of preparing analyte-monomer complexes before polymerization, model analytes (trifluralin and carbaryl) were directly dissolved in a polyacrylonitrile (PAN) solution, then electrospun into nanofibrous mats. This allowed for a means of preparation of highly crystalline, template-imprinted nanostructures with minimal synthetic complexity.Following the characterization studies for the new material, the extraction properties of the imprinted and nonimprinted electrospun mats were investigated in thin film microextraction (TFME …
Anahtar Kelimeler
Electrospinning | Molecularly imprinted polymer | Pesticides | Sample preparation | Thin film microextraction