| Yazarlar (4) |
Ozcan Yalcinkaya
Gazi University, Türkiye |
|
Hakan Erdogan
Gazi University, Türkiye |
Prof. Dr. Harun ÇİFTÇİ
Kırşehir Ahi Evran Üniversitesi, Türkiye |
|
Ali Rehber Turker
Gazi University, Türkiye |
| Özet |
| This study presents a chelating agent free solid phase extraction method for preconcentration of Al(III) using hybrid nano zirconium dioxide-boron oxide (ZrO2/B2O3) sorbent. This method is based on the sorption of Al(III) ions directly onto nano sorbent, followed by the elution with 10 mL of 4 mol L-1 HNO3 and determination by flame atomic absorption spectrometry (FAAS). Preconcentration parameters, including pH of the sample solution, volume and concentration of the eluent, sample volume, and flow rate of the sample solution, that affect the recovery of the Al(III) ions have been optimized. Under the optimized experimental conditions, analytical parameters such as limit of detection, limit of quantification, linear working range, precision, and accuracy were determined. The analytical limit of detection for Al(III) was found as 7.71 mu g L-1. The reusability and adsorption capacity of the new hybrid sorbent for Al(III) ions were also investigated. Interfering effects of matrix constituent on the recovery of the Al(III) ions were studied. The accuracy of the method was checked by determining Al(III) ions in a certified reference water sample (SPS-WW1 Waste Water). The proposed procedure was applied for the determination of Al(III) ions in dam waters. |
| Anahtar Kelimeler |
| aluminum | flame atomic absorption spectrometry | nano sorbent | preconcentration | solid phase extraction |
| Bildiri Türü | Tebliğ/Bildiri |
| Bildiri Alt Türü | Tam Metin Olarak Yayınlanan Tebliğ (Uluslararası Kongre/Sempozyum) |
| Bildiri Niteliği | Web of Science Kapsamındaki Kongre/Sempozyum |
| DOI Numarası | 10.1080/00387010.2012.666700 |
| Bildiri Dili | İngilizce |
| Kongre Adı | 12th National Spectroscopy Congress |
| Kongre Tarihi | 18-05-2011 / 22-05-2011 |
| Basıldığı Ülke | Türkiye |
| Basıldığı Şehir | Antalya |
| Atıf Sayıları | |
| WoS | 20 |
