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Atatürk Üniversitesi, Türkiye |
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Türkiye |
Doç. Dr. Özlem GÜNDOĞDU AYTAÇ
Kırşehir Ahi Evran Üniversitesi, Türkiye |
Dr. Öğr. Üyesi Sertan AYTAÇ
Kırşehir Ahi Evran Üniversitesi, Türkiye |
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| Özet |
| To address the low corrosion resistance of conventional epoxy coatings, a smart nanocomposite was designed by using UiO-66-NH2, a metal–organic framework (MOF), loaded with a new Schiff base as an inhibitor. The MOFs were encapsulated with a pH-responsive shell, allowing for the controlled release of the inhibitor. The crystallinity of UiO-66-NH2 remained preserved after encapsulation, and spherical particles were observed with an apparent size increase following encapsulation. The specific surface area of UiO-66-NH2 decreased from 860.18 to 131.06 m2 g–1 and pore volume from 1.9745 to 0.2871 cm3 g–1, indicating efficient pore occupation by the inhibitor. This change resulted in a loading efficiency of 30.5% and an encapsulation efficiency of 43.9%, which contribute to the enhanced corrosion resistance of the coating. The encapsulated UiO-66-NH2 exhibited smart behavior, releasing the highest … |
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| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | ACS Omega |
| Dergi ISSN | 2470-1343 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q2 |
| Makale Dili | Türkçe |
| Basım Tarihi | 11-2025 |
| Cilt No | 10 |
| Sayı | 48 |
| Sayfalar | 58490 / 58513 |
| DOI Numarası | 10.1021/acsomega.5c06277 |
| Makale Linki | https://doi.org/10.1021/acsomega.5c06277 |