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Crystal structure, spectroscopic characterization, DFT calculations, and antidiabetic activity of silver (I) perchlorate complex with methyl 6-quinolyl ether    
Yazarlar (5)
Merve Nurhan Güney
Gazi Üniversitesi, Türkiye
Ceyhun Küçük
Zonguldak Bulent Ecevit University, Türkiye
Şenay Yurdakul
Gazi Üniversitesi, Türkiye
Namık Özdemir
Ondokuz Mayis Üniversitesi, Türkiye
Doç. Dr. Ebru ÇÖTELİ Doç. Dr. Ebru ÇÖTELİ
Kırşehir Ahi Evran Üniversitesi, Türkiye
Devamını Göster
Özet
The [Ag(C10H9NO)2]ClO4 complex was synthesized from the methyl 6-quinolyl ether (6-MQ) (C10H9NO) molecule, and this new structure was characterized by spectroscopic methods such as single-crystal X-ray diffraction, FT-IR, FT-Ra, ¹H, and ¹³C NMR. In addition, these spectroscopic data were combined with DFT calculations. The X-ray diffraction analysis revealed that the Ag(I) complex crystallized in the monoclinic system with the P21/n. The asymmetric unit of the compound comprises one Ag(I) cation, two methoxyquinoline ligands with the same distance [2.134 Å], and one ClO₄⁻ anion. Computational studies were performed by using the DFT approach on the present complex to get insight into the structural parameters, spectral characteristics, and electronic properties. The characterization results were found to be consistent with the proposed structure of the complex, and the DFT approach supported the …
Anahtar Kelimeler
Antidiabetic activity | Crystal structure | Methyl 6-quinolyl ether | Silver perchlorate complex | Vibrational spectra
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Journal of Molecular Structure
Dergi ISSN 0022-2860 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q2
Makale Dili İngilizce
Basım Tarihi 02-2025
Cilt No 1352
Sayı 1
DOI Numarası 10.1016/j.molstruc.2025.144550
Makale Linki https://doi.org/10.1016/j.molstruc.2025.144550