Bingol propolis self-assembled monolayer films: Preparation, characterization and application as corrosion inhibitors for copper protection in NaCl environment
Yazarlar (12)
Ramazan Solmaz Bingol University, Türkiye
Yesim Aydin Dursun Bingol University, Türkiye
Ece Altunbas Sahin Bingol University, Türkiye
Ibrahim Halil Gecibesler Bingol University, Türkiye
Mustafa Dogrubas Bingol University, Türkiye
Mehmet Tung Bingol University, Türkiye
Nevzat Caglayan Bingol University, Türkiye
Arş. Gör. İbrahim Baki ŞAHİN Kırşehir Ahi Evran Üniversitesi, Türkiye
Inan Dursun Bingol University, Türkiye
Sinan Bayindir Bingol University, Türkiye
Ibrahim Y. Erdogan Bingol University, Türkiye
Gulfeza Kardas Cukurova University, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı MATERIALS CHEMISTRY AND PHYSICS (Q2)
Dergi ISSN 0254-0584 Wos Dergi Scopus Dergi
Makale Dili İngilizce Basım Tarihi 03-2024
Cilt / Sayı / Sayfa 315 / 0 / – DOI 10.1016/j.matchemphys.2024.128956
Özet
Protective thin films prepared from natural products can be used as an economical, efficient and environmentally friendly method to mitigation corrosion. The aim of this study is to prepare self -assembled monolayer (SAM) films of Bingo center dot l propolis (B -PP) sourced from the northern regions of Bingo center dot l province (Adakli, Kigi, Yayladere, and Yedisu) under various experimental conditions for the protection of copper against corrosion in a 3.5 % NaCl environment. The B-PP/SAM films were prepared under various conditions including different solvents, film formation times, and B -PP concentrations. The protective performance of the B-PP/SAM films was evaluated using various electrochemical techniques and the films were characterized using various surface characterization techniques. It was found that highly adherent, dense and aesthetically pleasing B-PP/SAM films were homogenously prepared on the copper surface. The assembly conditions significantly influence both the appearance and electrochemical properties of the films. The most effective B-PP/SAM films for copper protection were prepared using ethanol as a solvent containing 1000 ppm B -PP after a 24 h film formation time. According to potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and linear polarization resistance (LPR) results, the protection efficiencies were 95.3 %, 95.5 % and 96.8 %, respectively.
Anahtar Kelimeler
Self-assembly monolayer films | Bingo center dot l propolis | Natural products | Copper protection | Corrosion inhibition