| Yazarlar (6) |
Öğr. Gör. Fatih ÖKSÜZOĞLU
|
Şule Ateş
Selçuk Üniversitesi, Türkiye |
|
Osman Murat Özkendir
Tarsus Üniversitesi, Türkiye |
|
Gültekin Çelik
Selçuk Üniversitesi, Türkiye |
|
Yasin Ramazan Eker
Necmettin Erbakan Üniversitesi, Türkiye |
|
Hadi Baveghar
|
| Özet |
| The increasing demand for safe and high-energy-density battery systems has led to intense research into solid electrolytes for rechargeable batteries. One of these solid electrolytes is the NASICON-type LiAlTi(PO) (LATP) material. In this study, different boron compounds (10% BO doped, 10% HBO doped, and 5% BO + 5% HBO doped) were doped at total 10 wt.% into the Ti sites of an LATP solid electrolyte to investigate the structural properties and ionic conductivity of solid electrolytes using the solid-state synthesis method. Characterization of the synthesized samples was conducted using X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), and electrochemical impedance spectroscopy (EIS). The XRD patterns of the boron-doped LATP (LABTP) samples show that the samples have a rhombohedral phase with space group R3¯c together and low amounts of impurity phases. While all the LABTP samples exhibited similar ionic conductivity values of around 10 S cm, the LABTP2 sample doped with 10 wt.% HBO demonstrated the highest ionic conductivity. These findings suggest that varying B ion doping strategies in LATP can significantly advance the development of solid electrolytes for all-solid-state lithium-ion batteries. |
| Anahtar Kelimeler |
| LATP solid electrolyte | boron doping | crystal structure | ionic conductivity |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Materials |
| Dergi ISSN | 1996-1944 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q1 |
| Makale Dili | Türkçe |
| Basım Tarihi | 08-2024 |
| Cilt No | 17 |
| Sayı | 15 |
| Doi Numarası | 10.3390/ma17153846 |
| Makale Linki | https://doi.org/10.3390/ma17153846 |
| Atıf Sayıları | |
| WoS | 3 |
