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Structure and ionic conductivity of NASICON-type LATP solid electrolyte synthesized by the solid-state method    
Yazarlar (6)
Öğr. Gör. Fatih ÖKSÜZOĞLU Öğr. Gör. Fatih ÖKSÜZOĞLU
Kırşehir Ahi Evran Üniversitesi, Türkiye
Şule Ateş
Selcuk University, Türkiye
Osman Murat Özkendir
Tarsus University, Türkiye
Gültekin Çelik
Selcuk University, Türkiye
Yasin Ramazan Eker
Necmettin Erbakan University, Türkiye
Hadi Baveghar
Selcuk University, Türkiye
Devamını Göster
Özet
The area of commercial battery innovation to replace safer batteries in widely used secondary batteries offers promising research into solid-state electrolytes (SSEs). Compared to lithium-ion electrolytes, solid-state electrolytes are inherently safer because they replace solvents with non-flammable materials. One of the promising materials for electrolytes today is based on inorganic materials, especially ceramics. Ceramics with superior mechanical, chemical and electrochemical stability and stability against high temperatures are of great interest. NASICON structured Li1.3 Al0.3 Ti1.7 (PO4)3 (LATP) is the most studied type of solid electrolyte due to its stability against air and humidity and high ionic conductivity. In this study, LATP samples were synthesized by solid-state synthesis method. The structural, morphological and charge transport properties (ionic conductivities) of the synthesized samples were characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). Since the modifications applied during the sample preparation process can change the crystal structure and size of the target material, in this study, in order to minimize the formation of impurity phases and to achieve high ionic conductivity it was applied the different synthesis steps (temperature, time, grinding speed, etc.) from the literature. While the ionic conductivity value obtained is among the best values obtained by LATP synthesis methods in the literature, it is the best ionic conductivity value (1.3 x 10-3 S cm-1) obtained by the solid state synthesis method.
Anahtar Kelimeler
Solid -state batteries | LATP electrolyte | Solid -state method
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Ceramics International
Dergi ISSN 0272-8842 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q1
Makale Dili Türkçe
Basım Tarihi 09-2024
Cilt No 50
Sayı 17
Sayfalar 31435 / 31441
DOI Numarası 10.1016/j.ceramint.2024.05.450
Makale Linki https://doi.org/10.1016/j.ceramint.2024.05.450