| Yazarlar (3) |
|
Dicle Üniversitesi, Türkiye |
|
Dicle Üniversitesi, Türkiye |
Prof. Dr. Nadir DEMİREL
Kırşehir Ahi Evran Üniversitesi, Türkiye |
| Özet |
| Chiral Schiff-bases 3a-f based on ferrocene were designed and synthesized using solvent-free methods by mixing ferrocene carbaldehyde 1 with amino alcohols and amines 2a-f under microwave irradiation and classical method for the enantioselective nitroaldol (Henry) reaction. The Schiff-bases were obtained in shorter reaction times and improved yield under microwave irradiation method over classical method. The highest enantioselectivity was observed in ligand 3e (95% ee) when CH |
| Anahtar Kelimeler |
| chiral Schiff-bases | ferrocene | Henry reaction | microwave irradiation | nitro aldol reaction |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayınlanan tam makale |
| Dergi Adı | Chirality |
| Dergi ISSN | 0899-0042 Wos Dergi Scopus Dergi |
| Makale Dili | İngilizce |
| Basım Tarihi | 05-2011 |
| Cilt No | 23 |
| Sayı | 5 |
| Sayfalar | 374 / 378 |
| Doi Numarası | 10.1002/chir.20934 |