Solvent-free synthesis of chiral Schiff-base ligands based on ferrocene under microwave irradiation and application to enantioselective nitroaldol (Henry) reaction
Yazarlar (3)
Gülşen Öztürk Dicle Üniversitesi, Türkiye
Doç. Dr. Mehmet Çolak Dicle Üniversitesi, Türkiye
Prof. Dr. Nadir DEMİREL Kırşehir Ahi Evran Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Chirality (Q2) | ||
| Dergi ISSN | 0899-0042 Dergi Bilgileri (2011) | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2011 |
| Cilt / Sayı / Sayfa | 23 / 5 / 374–378 | DOI | 10.1002/chir.20934 |
| Makale Linki | https://onlinelibrary.wiley.com/doi/abs/10.1002/chir.20934 | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| Chiral Schiff‐bases 3a, 3b, 3c, 3d, 3e, 3f based on ferrocene were designed and synthesized using solvent‐free methods by mixing ferrocene carbaldehyde 1 with amino alcohols and amines 2a, 2b, 2c, 2d, 2e, 2f under microwave irradiation and classical method for the enantioselective nitroaldol (Henry) reaction. The Schiff‐bases were obtained in shorter reaction times and improved yield under microwave irradiation method over classical method. The highest enantioselectivity was observed in ligand 3e (95% ee) when CH2Cl2 was used as solvent. Chirality, 2011. © 2011 Wiley‐Liss, Inc. |
| Anahtar Kelimeler |
| chiral Schiff-bases | ferrocene | Henry reaction | microwave irradiation | nitro aldol reaction |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 7 |
| Scopus | 7 |
| Google Scholar | 8 |