Yazarlar (2) |
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![]() Ahi Evran Üniversitesi, Türkiye |
Özet |
In this study, a novel chiral inda (box) ligand 1 with a norbornadiene backbone was synthesized and used as a chiral ligand in the copper-catalyzed enantioselective Henry reaction, one of the important C-C bond forming reactions in organic chemistry [1-2]. The synthesis of the ligand was achieved in 2 steps starting from diacyl chloride 2 and (1R, 2S)-cis-1-amino-2-indanol (3). The formed bis (hydroxyamide) was cyclized in the presence of Ti (iPrO) 4 at 135 C to give inda (box) ligand 1 in 75% yield (Scheme 1). |
Anahtar Kelimeler |
Bildiri Türü | Tebliğ/Bildiri |
Bildiri Alt Türü | Özet Metin Olarak Yayınlanan Tebliğ (Uluslararası Kongre/Sempozyum) |
Bildiri Niteliği | Alanında Hakemli Uluslararası Kongre/Sempozyum |
Bildiri Dili | İngilizce |
Kongre Adı | WITAM-2016 2nd INTERNATIONAL CONGRESS ON THE WORLD OF TECHNOLOGY AND ADVANCED MATERIALS |
Kongre Tarihi | 28-09-2016 / 02-10-2016 |
Basıldığı Ülke | Türkiye |
Basıldığı Şehir | Kırşehir |