Different Reactivities of Alkoxy and Thiocarbene Complexes of Fischer Type Formation of N Enamino ethoxycarbene Complexes and Quinolines Respectively
Yazarlar (2)
Prof. Dr. Betül KARATAŞ Kırşehir Ahi Evran Üniversitesi, Türkiye
Rudolf Aumann University Of Münster
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Organometallics | ||
| Dergi ISSN | 0276-7333 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2010 |
| Kabul Tarihi | 12-04-2026 | Yayınlanma Tarihi | – |
| Cilt / Sayı / Sayfa | 29 / 4 / 801–805 | DOI | 10.1021/om900807s |
| Makale Linki | http://pubs.acs.org/doi/abs/10.1021/om900807s | ||
| Özet |
| Alkoxy- and thiocarbene complexes of chromium and tungsten afford different type of products on reaction with (N-aryl)imidoyl chlorides. The (n-butyl)ethoxycarbene complex [(OC)5WC(OEt)n-Bu] and (N-aryl)imidoyl chlorides t-BuClCNC6H4R4 (R4 = H, OMe) undergo a rearrangement to (N-enamino)ethoxycarbene complexes, whereas quinolines are obtained from the corresponding reaction of (alkyl)thiocarbene complexes [(OC)5MC(SEt)CH2R] (M = W, Cr; R = n-Pr, Me) with (N-aryl)imidoyl chlorides R1ClCNC6H2R2R3R4 (R1 = t-Bu, Ph; R2, R3 = H, HCCH−CHCH; R4 = H, OMe, Me) by β-cyclization. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 9 |