Controlled Synthesis of Substituted Benzobasketene Derivatives
Yazarlar (5)
Prof. Dr. Betül KARATAŞ Orta Doğu Teknik Üniversitesi, Türkiye
Murat Çelik Atatürk Üniversitesi, Türkiye
Mehmet Serdar Gültekin Atatürk Üniversitesi, Türkiye
Orhan Uzun Bülent Ecevit Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Helvetica Chimica Acta | ||
| Dergi ISSN | 0018-019X Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2003 |
| Cilt / Sayı / Sayfa | 86 / 10 / 3332–3341 | DOI | 10.1002/hlca.200390276 |
| Makale Linki | https://hdl.handle.net/11511/56422 | ||
| Özet |
| AbstractThe addition of benzyne to trans‐7,8‐dibromobicyclo[4.2.0]octa‐2,4‐diene (6) led to the formation of dibromide 7. The dehydrobromination of 7 followed by replacement of the Br‐atom with a CN substituent gave 9. Photolysis of 9 in acetone at 254 nm yielded the desired monosubstituted benzobasketene derivative 10. Bromination of monobromide 8 followed by dehydrobromination furnished the symmetrically substituted dibromo compound 15. Further bromination of 7 followed by dehydrobromination resulted in the formation of the dibromides 20 and 21. Substitution of the Br‐atoms in 15, 20, and 21 with CN substituents and photolysis of the formed dicarbonitriles 16, 23, and 24 gave the target benzobasketene‐dicarbonitriles 17, 25, and 26, respectively. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |