Preparation of fibrous polymer grafted magnetic chitosan beads and modified with hydrazone and imidazole groups: isolation of U(VI) ions from seawater
    
Yazarlar (5)
Serhad Tilki
Gazi Üniversitesi, Türkiye
Ömür Çelikbıçak
Hacettepe Üniversitesi, Türkiye
Prof. Dr. İlkay AÇIKGÖZ ERKAYA Kırşehir Ahi Evran Üniversitesi, Türkiye
Mehmet Yakup Arıca
Gazi Üniversitesi, Türkiye
Gülay Bayramoğlu
Gazi Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Radioanalytical and Nuclear Chemistry (Q3)
Dergi ISSN 0236-5731 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 03-2025
Cilt / Sayı / Sayfa 334 / 5 / 3319–3334 DOI 10.1007/s10967-025-10065-7
Makale Linki https://doi.org/10.1007/s10967-025-10065-7
Özet
The magnetic chitosan beads were prepared and grafted with glycidylmethacrylate, then diaminomelanonitrile (DAMN) was attached. The nitrile groups of DAMN were reacted with hydrazine hydrate hydrochloride and hydrazine hydrate-ethylene diamine to obtain hydrazine (HYD) and imidazole (IMDZ) groups, respectively. Both adsorbents removed uranyl ions from the aqueous medium and seawater. The adsorption capacities of the Fe₃O₄@CHT@p(GMA)-HYD and Fe₃O₄@CHT@p(GMA)-IMDZ, beads were 328.4 and 434.7 mg/g, respectively. Both adsorbents have high performance for adsorbing U(VI) ions from seawater. The synthesized adsorbents were used to isolate U(VI) ions from seawater in the presence of various ions.
Anahtar Kelimeler
Adsorption | Chitosan-based adsorbent | Isotherms and Kinetics | Surface modification | Uranium