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Atomic Layer Deposition of NiOOH/Ni(OH)(2) on PIM-1-Based N-Doped Carbon Nanofibers for Electrochemical Water Splitting in Alkaline Medium         
Yazarlar
Bhushan Patil
Doç. Dr. Bekir SATILMIŞ
Ahi Evran Üniversitesi, Türkiye
Mohammad Aref Khalily
Tamer Uyar
Özet
Portable and flexible energy devices demand lightweight and highly efficient catalytic materials for use in energy devices. An efficient water splitting electrocatalyst is considered an ideal future energy source. Well-aligned high-surface-area electrospun polymers of intrinsic microporosity (PIM-1)-based nitrogen-doped carbon nanofibers were prepared as a free-standing flexible electrode. A non-noble-metal catalyst NiOOH/Ni(OH)(2) was precisely deposited over flexible free-standing carbon nanofibers by using atomic layer deposition (ALD). The morphology, high surface area, nitrogen doping, and Ni states synergistically showed a low onset potential ((HER)=-40 and (OER)=290mV vs. reversible hydrogen electrode), small overpotential at (10) [oxygen evolution reaction (OER)=390.5mV and hydrogen evolution reaction (HER)=-147mV], excellent kinetics (Tafel slopes for OER=50mVdec(-1) and HER=41mVdec(-1)), and high stability (>16h) towards water splitting in an alkaline medium (0.1m KOH). The performance was comparable with that of state-of-the-art noble-metal catalysts (e.g., Ir/C, Ru/C for OER, and Pt/C for HER). Post-catalytic characterization with X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy further proved the durability of the electrode. This study provides insight into the design of 1D-aligned N-doped PIM-1 electrospun carbon nanofibers as a flexible and free-standing NiOOH/Ni(OH)(2) decorated electrode as a highly stable nanocatalyst for water splitting in an alkaline medium.
Anahtar Kelimeler
atomic layer deposition | carbon fibers | electrospinning | nickel | water splitting
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı CHEMSUSCHEM
Dergi ISSN 1864-5631
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q1
Makale Dili İngilizce
Basım Tarihi 04-2019
Cilt No 12
Sayı 7
Sayfalar 1469 / 1477
Doi Numarası 10.1002/cssc.201802500
Makale Linki https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cssc.201802500