Atomic Layer Deposition of NiOOH/Ni(OH)(2) on PIM-1-Based N-Doped Carbon Nanofibers for Electrochemical Water Splitting in Alkaline Medium
 
Yazarlar (4)
Bhushan Patil Bilkent Üniversitesi, Türkiye
Doç. Dr. Bekir SAYGINER Kırşehir Ahi Evran Üniversitesi, Türkiye
Mohammad Aref Khalily Bilkent Üniversitesi, Türkiye
Tamer Uyar Bilkent Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Chemsuschem (Q1)
Dergi ISSN 1864-5631 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 04-2019
Cilt / Sayı / Sayfa 12 / 7 / 1469–1477 DOI 10.1002/cssc.201802500
Makale Linki https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cssc.201802500
Özet
Portable and flexible energy devices demand lightweight and highly efficient catalytic materials for use in energy devices. An efficient water splitting electrocatalyst is considered an ideal future energy source. Well‐aligned high‐surface‐area electrospun polymers of intrinsic microporosity (PIM‐1)‐based nitrogen‐doped carbon nanofibers were prepared as a free‐standing flexible electrode. A non‐noble‐metal catalyst NiOOH/Ni(OH)2 was precisely deposited over flexible free‐standing carbon nanofibers by using atomic layer deposition (ALD). The morphology, high surface area, nitrogen doping, and Ni states synergistically showed a low onset potential (ηHER=−40 and ηOER=290 mV vs. reversible hydrogen electrode), small overpotential at η10 [oxygen evolution reaction (OER)=390.5 mV and hydrogen evolution reaction (HER)=−147 mV], excellent kinetics (Tafel slopes for OER=50 mV dec−1 and HER …
Anahtar Kelimeler
atomic layer deposition | carbon fibers | electrospinning | nickel | water splitting