Enhancement of CO2 Affinity in a Polymer of Intrinsic Microporosity by Amine Modification
Yazarlar (10)
Christopher R. Mason The University Of Manchester, İngiltere
Louise Maynard-Atem The University Of Manchester, İngiltere
Kane W.J. Heard The University Of Manchester, İngiltere
Doç. Dr. Bekir SAYGINER The University Of Manchester, İngiltere
Peter M. Budd The University Of Manchester, İngiltere
Karel Friess University Of Chemistry And Technology, Prague, Çek Cumhuriyeti
Marek Lancì University Of Chemistry And Technology, Prague, Çek Cumhuriyeti
Paola Bernardo Cnr- Istituto Per La Tecnologia Delle Membrane, İtalya
Gabriele Clarizia Cnr- Istituto Per La Tecnologia Delle Membrane, İtalya
Johannes C. Jansen
Cnr- Istituto Per La Tecnologia Delle Membrane, İtalya
Cnr- Istituto Per La Tecnologia Delle Membrane, İtalya
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
|
||
| Dergi Adı | Macromolecules (Q1) | ||
| Dergi ISSN | 0024-9297 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2014 |
| Cilt / Sayı / Sayfa | 47 / 3 / 1021–1029 | DOI | 10.1021/ma401869p |
| Makale Linki | https://pubs.acs.org/doi/abs/10.1021/ma401869p | ||
| Özet |
| Nitrile groups in the polymer of intrinsic microporosity PIM-1 were reduced to primary amines using borane complexes. In adsorption experiments, the novel amine–PIM-1 showed higher CO2 uptake and higher CO2/N2 sorption selectivity than the parent polymer, with very evident dual-mode sorption behavior. In gas permeation with six light gases, the individual contributions of solubility and diffusion to the overall permeability was determined via time-lag analysis. The high CO2 affinity drastically restricts diffusion at low pressures and lowers CO2 permeability compared to the parent PIM-1. Furthermore, the size-sieving properties of the polymer are increased, which can be attributed to a higher stiffness of the system arising from hydrogen bonding of the amine groups. Thus, for the H2/CO2 gas pair, whereas PIM-1 favors CO2, amine–PIM-1 shows permselectivity toward H2, breaking the Robeson 2008 upper bound. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 286 |
| Scopus | 237 |
| Web of Science | 224 |