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Hydroxyalkylaminoalkylamide PIMs: Selective Adsorption by Ethanolamine- and Diethanolamine-Modified PIM-1       
Yazarlar
 Bekir SATILMIŞ Bekir SATILMIŞ
Türkiye
Mohammed N Alnajrani
Peter M. Budd
Özet
The polymer of intrinsic microporosity PIM-1 was modified by reaction with ethanolamine and with diethanolamine, and the modified polymers characterized by infrared spectroscopy, solid-state NMR spectroscopy, elemental analysis, thermogravimetric analysis and nitrogen adsorption. Various possible reaction products were considered, and the results indicated that hydroxyalkylaminoalkylamide structures were obtained. Gas adsorption measurements showed that ethanolamine modification increased the ideal CO2/N-2 selectivity. Studies of dye adsorption from aqueous solution demonstrated that the reaction products showed strong selectivity for the anionic dye Orange II, compared to the cationic dye Safranin O. Mass uptakes of the anionic dye by ethanolamine-modified PIM-1 samples were up to 2 orders of magnitude higher than for the parent polymer.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı MACROMOLECULES
Dergi ISSN 0024-9297
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 08-2015
Cilt No 48
Sayı 16
Sayfalar 5663 / 5669
Doi Numarası 10.1021/acs.macromol.5b01196
Makale Linki https://pubs.acs.org/doi/10.1021/acs.macromol.5b01196