Yazarlar |
Prof. Dr. Nadir DEMİREL
Kırşehir Ahi Evran Üniversitesi, Türkiye |
Y. Bulut
Dicle Üniversitesi, Turkey |
Özet |
A practical synthesis of chiral amine precursors 3 and 4 and chiral diaza 18-crown-6 ethers 5, 6 and 7 starting from chiral amines are reported. The molecular recognition of these chiral crown ethers for amino acids potassium and sodium salts has been characterized by UV-vis. The selectivity order is Phe>Thr>Ala. In the case of 6 the cavity of the macrocycle plays an important role in recognition. © 2003 Elsevier Ltd. All rights reserved. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
Dergi Adı | Tetrahedron Asymmetry |
Dergi ISSN | 0957-4166 |
Makale Dili | İngilizce |
Basım Tarihi | 09-2003 |
Cilt No | 14 |
Sayı | 17 |
Sayfalar | 2633 / 2637 |
Doi Numarası | 10.1016/S0957-4166(03)00594-9 |