| Yazarlar |
Serap Seyhan
Dokuz Eylül Üniversitesi, Turkey |
|
Melek Merdivan
Dokuz Eylül Üniversitesi, Turkey |
|
Nadir Demirel
Dicle Üniversitesi, Turkey |
|
Halil Hosgoren
Dicle Üniversitesi, Turkey |
| Özet |
| 5,10,15,20-tetrakis(phenoxy acetic acid) porphyrin (PAAP) was covalently linked to Merrifield chloromethylated resin. Characterization of PAAP and the modified polymeric matrix were performed by 1H NMR, FTIR and elemental analysis. The sorbent was used for the separation and enrichment of the d-electron metals (Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)) at pH 6-8 and of the f-electron metals U(VI) and Th(IV) at pH 4-5. The metals ions were preconcentrated with a concentration factor range of 115-215 and then determined by flame atomic absorption spectrometry or visible spectrophotometry using Arsenazo(III). The retained metals were eluted with 2.0 mol L-1 HNO3 in the case of the d-electron metals and 0.1/0.25 mol L -1 HCl in the case of the f-electron metals. The procedure was validated by analyzing the NIST standard reference material 2709 (San Joaquin Soil). © 2007 Springer-Verlag. |
| Anahtar Kelimeler |
| d- and f-electron metals | Merrifield chloromethylated resin | Porphyrin | Preconcentration |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | Microchimica Acta |
| Dergi ISSN | 0026-3672 |
| Makale Dili | İngilizce |
| Basım Tarihi | 04-2008 |
| Cilt No | 161 |
| Sayı | 1 |
| Sayfalar | 87 / 93 |
| Doi Numarası | 10.1007/s00604-007-0797-9 |
| Atıf Sayıları | |
| SCOPUS | 10 |
