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Polymer supported 5,10,15,20-tetrakis(phenoxy acetic acid)porphyrin derivative for separation and preconcentration of d- and f-electron metals  
Yazarlar
Serap Seyhan
Dokuz Eylül Üniversitesi, Turkey
Melek Merdivan
Dokuz Eylül Üniversitesi, Turkey
Prof. Dr. Nadir DEMİREL Prof. Dr. Nadir DEMİREL
Kırşehir Ahi Evran Üniversitesi, Türkiye
Halil Hosgoren
Dicle Üniversitesi, Turkey
Özet
5,10,15,20-tetrakis(phenoxy acetic acid) porphyrin (PAAP) was covalently linked to Merrifield chloromethylated resin. Characterization of PAAP and the modified polymeric matrix were performed by 1H NMR, FTIR and elemental analysis. The sorbent was used for the separation and enrichment of the d-electron metals (Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)) at pH 6-8 and of the f-electron metals U(VI) and Th(IV) at pH 4-5. The metals ions were preconcentrated with a concentration factor range of 115-215 and then determined by flame atomic absorption spectrometry or visible spectrophotometry using Arsenazo(III). The retained metals were eluted with 2.0 mol L-1 HNO3 in the case of the d-electron metals and 0.1/0.25 mol L -1 HCl in the case of the f-electron metals. The procedure was validated by analyzing the NIST standard reference material 2709 (San Joaquin Soil). © 2007 Springer-Verlag.
Anahtar Kelimeler
d- and f-electron metals | Merrifield chloromethylated resin | Porphyrin | Preconcentration
Makale Türü Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayımlanan tam makale
Dergi Adı Microchimica Acta
Dergi ISSN 0026-3672
Makale Dili İngilizce
Basım Tarihi 04-2008
Cilt No 161
Sayı 1
Sayfalar 87 / 93
Doi Numarası 10.1007/s00604-007-0797-9