| Yazarlar |
Gülşen Öztürk
Dicle Üniversitesi, Turkey |
|
Mehmet Çolak
Dicle Üniversitesi, Turkey |
|
Nadir Demirel
Kırşehir Ahi Evran Üniversitesi, Turkey |
| Özet |
| Chiral Schiff-bases 3a-f based on ferrocene were designed and synthesized using solvent-free methods by mixing ferrocene carbaldehyde 1 with amino alcohols and amines 2a-f under microwave irradiation and classical method for the enantioselective nitroaldol (Henry) reaction. The Schiff-bases were obtained in shorter reaction times and improved yield under microwave irradiation method over classical method. The highest enantioselectivity was observed in ligand 3e (95% ee) when CH2Cl2 was used as solvent. © 2011 Wiley-Liss, Inc. |
| Anahtar Kelimeler |
| chiral Schiff-bases | ferrocene | Henry reaction | microwave irradiation | nitro aldol reaction |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | Chirality |
| Dergi ISSN | 0899-0042 |
| Makale Dili | İngilizce |
| Basım Tarihi | 05-2011 |
| Cilt No | 23 |
| Sayı | 5 |
| Sayfalar | 374 / 378 |
| Doi Numarası | 10.1002/chir.20934 |
| Atıf Sayıları | |
| SCOPUS | 6 |
