| Yazarlar |
Öğr. Gör. Nuray ÖZTÜRK
Kırşehir Ahi Evran Üniversitesi, Türkiye |
Betül Yilmaz
Ondokuz Mayis Üniversitesi, Turkey |
|
Hümeyra Bati
Ondokuz Mayis Üniversitesi, Turkey |
|
Esat Bozkurt
Ondokuz Mayis Üniversitesi, Turkey |
|
Orhan Büyükgüngör
Ondokuz Mayis Üniversitesi, Turkey |
| Özet |
| A novel heterodinuclear complex formed by the reaction of silver nitrate with Schiff base complex of copper(II) has been synthesized and characterized by Infrared (IR), ultraviolet-visible (UV-VIS), electron paramagnetic resonance (EPR) and X-ray diffraction methods. Preparation and crystal structure of the heterodinuclear complex, LCuAgNO3, (L = N,N′-ethylenebis(3- methoxysalicylideneimine) are reported. The crystal structure consists of ordered dinuclear units with CuII and AgI ions are bridged by two oxygen atoms of Schiff base ligand. The copper(II) ion has a distorted square-planar geometry involving the N2O2 donor set of Schiff base ligand. The g-values were calculated for title complex both in polycrystalline state at 298 K and in frozen DMF (113 K). The evaluated metal-ligand bonding parameters showed strong in-plane σ bonding. © 2012 Published by Elsevier B.V. All rights reserved. |
| Anahtar Kelimeler |
| Crystal structure | EPR | IR | UV | X-ray diffraction |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy |
| Dergi ISSN | 1386-1425 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2013 |
| Cilt No | 101 |
| Sayı | 1 |
| Sayfalar | 167 / 171 |
| Doi Numarası | 10.1016/j.saa.2012.09.063 |
| Atıf Sayıları | |
| SCOPUS | 4 |
