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Spectroscopy and X-ray studies of {{6,6′-dimethoxy-2,2′- [ethane-1,2-diyl-bis-(nitrilomethylidyne)]diphenolato}(aqua)-dioxouranium(VI)} dehydrate  
Yazarlar
Ç Yüksektepe Ataol
Çankiri Karatekin Üniversitesi, Turkey
Öğr. Gör. Nuray ÖZTÜRK Öğr. Gör. Nuray ÖZTÜRK
Kırşehir Ahi Evran Üniversitesi, Türkiye
H. Bat
Ondokuz Mayis Üniversitesi, Turkey
Özet
The C18H20N2O7U · 2H2O (I) complex has been prepared and characterized by single crystal X-ray diffraction properties (CIF file CCDC no. 913243). The title compound crystallizes in the orthorhombic system, space group Pbca with a = 19.542(5), b = 9.916(5), c = 21.940(5) Å, V = 4252(3) Å3 and Z = 8. In complex I, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand and water molecule in the equatorial plane and oxo atoms in the axial positions. The crystal packing occurs intra-inter molecular hydrogen bonds. © 2014 Pleiades Publishing, Ltd.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayımlanan tam makale
Dergi Adı Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Dergi ISSN 1070-3284
Makale Dili İngilizce
Basım Tarihi 01-2014
Cilt No 40
Sayı 9
Sayfalar 671 / 675
Doi Numarası 10.1134/S1070328414090139