Spectroscopy and X-ray studies of {{6,6′-dimethoxy-2,2′- [ethane-1,2-diyl-bis-(nitrilomethylidyne)]diphenolato}(aqua)-dioxouranium(VI)} dehydrate   
Yazarlar (3)
Ç Yüksektepe Ataol
Çankiri Karatekin Üniversitesi, Türkiye
Öğr. Gör. Nuray ÖZTÜRK Ondokuz Mayis Üniversitesi, Türkiye
H. Bat
Ondokuz Mayis Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayınlanan tam makale
Dergi Adı Russian Journal of Coordination Chemistry Koordinatsionnaya Khimiya
Dergi ISSN 1070-3284 Wos Dergi Scopus Dergi
Makale Dili İngilizce
Basım Tarihi 01-2014
Cilt No 40
Sayı 9
Sayfalar 671 / 675
DOI Numarası 10.1134/S1070328414090139
Özet
The C18H20N2O7U · 2H2O (I) complex has been prepared and characterized by single crystal X-ray diffraction properties (CIF file CCDC no. 913243). The title compound crystallizes in the orthorhombic system, space group Pbca with a = 19.542(5), b = 9.916(5), c = 21.940(5) Å, V = 4252(3) Å3 and Z = 8. In complex I, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand and water molecule in the equatorial plane and oxo atoms in the axial positions. The crystal packing occurs intra-inter molecular hydrogen bonds. © 2014 Pleiades Publishing, Ltd.
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