| Yazarlar |
Öğr. Gör. Nuray ÖZTÜRK
Kırşehir Ahi Evran Üniversitesi, Türkiye |
C. Y. Ataol
Çankiri Karatekin Üniversitesi, Turkey |
|
H. BatI
Ondokuz Mayis Üniversitesi, Turkey |
| Özet |
| The C30H30N4O10S2U complex (I) has been investigated and characterized by single crystal X-ray diffraction (CIF file CCDC no. 970349), IR and UV-Vis spectroscopic techniques. X-ray results show that the title compound crystallizes in the monoclinic system, space group P21/c with a = 14.8219(14), b = 11.6177(11), c = 20.0854(15) Å, β = 104.268(9)°, V = 3351.9(5) Å3 and Z = 4. In the title structure, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand in the equatorial plane and oxo atoms in the axial positions. The C-S-N(H)-N linkage is non-planar, the torsion angle being -98.7(15)° and the S atom showing a tetrahedral environment. The crystal packing occurs intra-inter molecular N-H⋯O and C-H⋯O hydrogen bonds. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
| Dergi ISSN | 1070-3284 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2014 |
| Cilt No | 40 |
| Sayı | 11 |
| Sayfalar | 849 / 853 |
| Doi Numarası | 10.1134/S1070328414110062 |
| Atıf Sayıları | |
| SCOPUS | 5 |
