Synthesis, spectroscopy and X-ray studies of [N′-(2-hydroxy-3-methoxybenzylidene)-4-methylbenzenesulfonohydrazide]uranyl(IV)
Yazarlar (3)
Öğr. Gör. Nuray ÖZTÜRK Ondokuz Mayis Üniversitesi, Türkiye
C. Y. Ataol Çankiri Karatekin Üniversitesi, Türkiye
H. Batı Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Russian Journal of Coordination Chemistry Koordinatsionnaya Khimiya (Q4) | ||
| Dergi ISSN | 1070-3284 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 11-2014 |
| Cilt / Sayı / Sayfa | 40 / 11 / 849–853 | DOI | 10.1134/S1070328414110062 |
| Makale Linki | https://doi.org/10.1134/s1070328414110062 | ||
| Özet |
| The C30H30N4O10S2U complex (I) has been investigated and characterized by single crystal X-ray diffraction (CIF file CCDC no. 970349), IR and UV-Vis spectroscopic techniques. X-ray results show that the title compound crystallizes in the monoclinic system, space group P21/c with a = 14.8219(14), b = 11.6177(11), c = 20.0854(15) Å, β = 104.268(9)°, V = 3351.9(5) Å3 and Z = 4. In the title structure, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand in the equatorial plane and oxo atoms in the axial positions. The C-S-N(H)-N linkage is non-planar, the torsion angle being -98.7(15)° and the S atom showing a tetrahedral environment. The crystal packing occurs intra-inter molecular N-H⋯O and C-H⋯O hydrogen bonds. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 5 |