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Comperative Evaluation of Anion-Doped Photocatalysts on the Mineralization and Decolorization of Natural Organic Matter   
Yazarlar (7)
Nazmiye Cemre Birben
Türkiye
Ceyda Senem Uyguner Demirel
Boğaziçi Üniversitesi, Türkiye
Sibel Sen Kavurmaci
Yelda Yalçın Gürkan
Tekirdağ Namık Kemal Üniversitesi, Türkiye
Doç. Dr. Ümit Nazlı TÜRKTEN Doç. Dr. Ümit Nazlı TÜRKTEN
Yildiz Technical University, Türkiye
Zekiye Cinar
Miray Bekbolet
Devamını Göster
Özet
The aim of this study was to assess photocatalytic performance of various anion doped TiO2 specimens on the degradation of natural organic matter represented by humic acids. Nitrogen doped (N-doped), sulfur doped (S-doped) and sulfur-nitrogen co-doped (S-N co-doped) TiO2 specimens were prepared according to a wet impregnation method. Their photocatalytic activities were evaluated with regard to degradation kinetics of humic acid in terms of UV-vis spectroscopic parameters (Color(436) and UV254) and dissolved organic carbon (DOC) as indicators of decolorization and mineralization respectively. The presence of different dopants in TiO2 structure ended up differences in terms of decolorization and mineralization kinetics of humic acids. Moreover, use of pure anatase form of TiO2 (Hombikat UV-100) for anion doping came up with higher photocatalytic activity than anion doped TiO2 specimens prepared by using TiO2 composed of mixture of anatase and rutile (Degussa P-25). Humic acid fluorescence excitation emission matrix (EEM) contour plots showed that solar photocatalytic degradation pathway was TiO2 type specific irrespective of dopants. (C) 2014 Elsevier B.V. All rights reserved.
Anahtar Kelimeler
Doped TiO2 | EEM fluorescence | Humic acid | Solar photocatalytic degradation
Bildiri Türü Tebliğ/Bildiri
Bildiri Alt Türü Özet Metin Olarak Yayınlanan Tebliğ (Uluslararası Kongre/Sempozyum)
Bildiri Niteliği Web of Science Kapsamındaki Kongre/Sempozyum
DOI Numarası 10.1016/j.cattod.2014.04.020
Bildiri Dili İngilizce
Kongre Adı The 3rd European Conference on Environmental Applications of Advanced Oxidation Processes
Kongre Tarihi 27-10-2013 / 30-10-2013
Basıldığı Ülke İspanya
Basıldığı Şehir Almeria