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Characterization of nineteen antimony III complexes as potent inhibitors of photosystem II carbonic anhydrase and glutathione reductase        
Yazarlar
Mehmet Sayım Karacan
Gazi Üniversitesi, Türkiye
Rodionova Margarita V
Doç. Dr. Turgay TUNÇ
Ahi Evran Üniversitesi, Türkiye
Kübra Begüm Venedik
Serhat Mamaş
Shitov Alexandr V
Zharmukhamedov Sergei K
Vyacheslav V Klimov
Nurcan Karacan
Gazi Üniversitesi, Türkiye
Suleyman I Allakhverdiev
Özet
Nineteen antimony(III) complexes were obtained and examined as possible herbicides. Six of these were synthesized for the first time, and their structures were identified using elemental analyses, H-1-NMR, C-13-NMR, FTIR, LCMS, magnetic susceptibility, and conductivity measurement techniques. For the nineteen examined antimony(III) complexes their most-stable forms were determined by DFT/B3LYP/LanL2DZ calculation method. These compounds were examined for effects on photosynthetic electron transfer and carbonic anhydrase activity of photosystem II, and glutathione reductase from chloroplast as well were investigated. Our results indicated that all antimony(III) complexes inhibited glutathione reductase activity of chloroplast. A number of these also exhibited good inhibitory efficiency of the photosynthetic and carbonic anhydrase activity of Photosystem II.
Anahtar Kelimeler
Photosystem II (PSII), Carbonic anhydrase, Glutathione reductase, Antimony(III) complexes, Inhibitors
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Photosynthesis Research
Dergi ISSN 0166-8595
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 12-2016
Cilt No 130
Sayı 1
Sayfalar 167 / 182
Doi Numarası 10.1007/s11120-016-0236-z
Makale Linki http://link.springer.com/10.1007/s11120-016-0236-z