Characterization of nineteen antimony III complexes as potent inhibitors of photosystem II carbonic anhydrase and glutathione reductase
      
Yazarlar (10)
Mehmet Sayım Karacan
Gazi Üniversitesi, Türkiye
Margarita V. Rodionova
Timiryazev Institute Of Plant Physiology, Russian Academy Of Sciences, Rusya Federasyonu
Doç. Dr. Turgay TUNÇ Kırşehir Ahi Evran Üniversitesi, Türkiye
Kübra Begüm Venedik
Gazi Üniversitesi, Türkiye
Serhat Mamaş
Gazi Üniversitesi, Türkiye
Alexandr V. Shitov
Institute Of Fundamental Problems Of Biology Of The Russian Academy Of Sciences, Rusya Federasyonu
Sergei K. Zharmukhamedov
Institute Of Fundamental Problems Of Biology Of The Russian Academy Of Sciences, Rusya Federasyonu
Vyacheslav V. Klimov
Institute Of Fundamental Problems Of Biology Of The Russian Academy Of Sciences, Rusya Federasyonu
Nurcan Karacan
Gazi Üniversitesi, Türkiye
Suleyman I. Allakhverdiev
Timiryazev Institute Of Plant Physiology, Russian Academy Of Sciences, Rusya Federasyonu
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Photosynthesis Research
Dergi ISSN 0166-8595 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 12-2016
Cilt / Sayı / Sayfa 130 / 1 / 167–182 DOI 10.1007/s11120-016-0236-z
Makale Linki http://link.springer.com/10.1007/s11120-016-0236-z
Özet
Nineteen antimony(III) complexes were obtained and examined as possible herbicides. Six of these were synthesized for the first time, and their structures were identified using elemental analyses, H-1-NMR, C-13-NMR, FTIR, LCMS, magnetic susceptibility, and conductivity measurement techniques. For the nineteen examined antimony(III) complexes their most-stable forms were determined by DFT/B3LYP/LanL2DZ calculation method. These compounds were examined for effects on photosynthetic electron transfer and carbonic anhydrase activity of photosystem II, and glutathione reductase from chloroplast as well were investigated. Our results indicated that all antimony(III) complexes inhibited glutathione reductase activity of chloroplast. A number of these also exhibited good inhibitory efficiency of the photosynthetic and carbonic anhydrase activity of Photosystem II.
Anahtar Kelimeler
Antimony(III) complexes | Carbonic anhydrase | Glutathione reductase | Inhibitors | Photosystem II (PSII)