Four and six-coordinated cobalt complexes based on thiosemicarbazone. Formation, experimental and theoretical characterization
Yazarlar (4)
Buşra Kaya İstanbul Üniversitesi-Cerrahpaşa, Türkiye
Prof. Dr. Tuncay KARAKURT Kırşehir Ahi Evran Üniversitesi, Türkiye
Onur Şahin Sinop Üniversitesi, Türkiye
Bahri Ülküseven
İstanbul Üniversitesi-Cerrahpaşa, Türkiye
İstanbul Üniversitesi-Cerrahpaşa, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure | ||
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2022 |
| Cilt / Sayı / Sayfa | 1250 / 1 / 131783–0 | DOI | 10.1016/j.molstruc.2021.131783 |
| Makale Linki | http://dx.doi.org/10.1016/j.molstruc.2021.131783 | ||
| Özet |
| The template reaction was performed between benzoylacetone-S-propylthiosemicarbazone and salicylaldehyde in the presence of Co(ClO4)2 and a square planar cobalt(II) complex, [Co(L)] (Co1) where L is a dibasic thiosemicarbazidato ligand was isolated. It was aimed to synthesize the octahedral cobalt complexes by using the co-ligands, pyridine and 2-amino pyridine. An octahedral cobalt(III) complex, [Co(L)(py)2]ClO4 (Co2), with two axial-pyridine ligands was obtained. Reaction with 2-amino pyridine gave an unexpected cobalt(III) centered structure, [Co(L1)]·H2O (Co3), where L1 is a new sixdentate (N4O2) ligand that yielded by the addition of the amino group of pyridine to the L ligand. L1 has tribasic thiosemicarbazidato structure that altered by the participation of an oxygen atom in addition to the amines. Experimental characterizations of three complexes have been completed using IR, NMR, UV–Vis, ESI … |
| Anahtar Kelimeler |
| Cobalt complexes | DFT | NLO | Thiosemicarbazone | X-ray diffraction |
Science Direct
Four and six-coordinated cobalt complexes based on thiosemicarbazone. Formation, experimental and theoretical characterization
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 7 |
| Scopus | 6 |
| Web of Science | 6 |