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Highly selective intermolecular one-pot three component 1,3-dipolar cycloaddition reaction of aldehydes, with phosphonates and proline   
Yazarlar
Dr. Öğr. Üyesi Nuriye Tuna SUBAŞI Dr. Öğr. Üyesi Nuriye Tuna SUBAŞI
Türkiye
Ayhan S Demir
Özet
The use of L-proline to act as an organocatalyst in the aldol reaction of acylphosphonates and non enolizable aldehydes failed; however, it reacted with the aldehydes to afford azomethine ylides after decarboxylation that in turn underwent 1,3-dipolar cycloaddition with the acylphosphonates to form a bicyclic hexahydropyrrolo[1,2-c]oxazol-1-ylphosphonates in good yield. No azomethine ylide formation was observed on the reaction of acylphosphonates with proline. (C) 2017 Elsevier Ltd. All rights reserved.
Anahtar Kelimeler
Dipolar cycloaddition | Proline | Acylphosphonate | Azomethine ylide
Bildiri Türü Tebliğ/Bildiri
Bildiri Alt Türü Özet Metin Olarak Yayımlanan Tebliğ (Uluslararası Kongre/Sempozyum)
Bildiri Niteliği Web of Science Kapsamındaki Kongre/Sempozyum
Bildiri Dili İngilizce
Kongre Adı 1st International Balkan Chemistry Congress (IBCC)
Kongre Tarihi 17-09-2018 / 20-09-2018
Basıldığı Ülke Türkiye
Basıldığı Şehir Edirne