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Manganese(III) acetate-mediated synthesis of biaryls under microwave irradiation     
Yazarlar
Ayhan S Demir
Hamide Fındık
Nezire Saygılı
Türkiye
Dr. Öğr. Üyesi Nuriye Tuna SUBAŞI Dr. Öğr. Üyesi Nuriye Tuna SUBAŞI
Ahi Evran Üniversitesi, Türkiye
Özet
Manganese(Ill) acetate (Mn(OAc)(3))-mediated synthesis of biaryls and heterobiaryls starting from arylboronic acid was developed under microwave irradiation in high yields Microwaves were also used for the synthesis of Mn(OAc)(3) from KMnO4 and acetic acid Additional irradiation of this in situ generated Mn(OAc)3 with arylboronic acids, which in turn furnished the biaryls in high yields In a one pot reaction This IS superior from the point of view of yield, short reaction time, sensitive functional group toleration, and more environmentally friendly than the reported methods with a minimum amount of benzene and thiophene as a reagent but not as a solvent (C) 2009 Elsevier Ltd All rights reserved
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı TETRAHEDRON
Dergi ISSN 0040-4020
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 02-2010
Cilt No 66
Sayı 6
Sayfalar 1308 / 1312
Doi Numarası 10.1016/j.tet.2009.12.018
Makale Linki http://dx.doi.org/10.1016/j.tet.2009.12.018