Manganese(III) acetate-mediated synthesis of biaryls under microwave irradiation
    
Yazarlar (4)
Ayhan S Demir
Middle East Technical University (Metu), Türkiye
Hamide Fındık
Middle East Technical University (Metu), Türkiye
Nezire Saygılı
Hacettepe Üniversitesi, Türkiye
Dr. Öğr. Üyesi Nuriye Tuna SUBAŞI Middle East Technical University (Metu), Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Tetrahedron
Dergi ISSN 0040-4020 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 02-2010
Cilt / Sayı / Sayfa 66 / 6 / 1308–1312 DOI 10.1016/j.tet.2009.12.018
Makale Linki http://dx.doi.org/10.1016/j.tet.2009.12.018
Özet
Manganese(Ill) acetate (Mn(OAc)(3))-mediated synthesis of biaryls and heterobiaryls starting from arylboronic acid was developed under microwave irradiation in high yields Microwaves were also used for the synthesis of Mn(OAc)(3) from KMnO4 and acetic acid Additional irradiation of this in situ generated Mn(OAc)3 with arylboronic acids, which in turn furnished the biaryls in high yields In a one pot reaction This IS superior from the point of view of yield, short reaction time, sensitive functional group toleration, and more environmentally friendly than the reported methods with a minimum amount of benzene and thiophene as a reagent but not as a solvent (C) 2009 Elsevier Ltd All rights reserved
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