Manganese(III) acetate-mediated synthesis of biaryls under microwave irradiation
Yazarlar (4)
Ayhan S Demir Middle East Technical University (Metu)
Hamide Fındık Middle East Technical University (Metu)
Nezire Saygılı Hacettepe Üniversitesi, Türkiye
Dr. Öğr. Üyesi Nuriye Tuna SUBAŞI Ahi Evran Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Tetrahedron
Dergi ISSN 0040-4020 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 02-2010
Kabul Tarihi 12-04-2026 Yayınlanma Tarihi
Cilt / Sayı / Sayfa 66 / 6 / 1308–1312 DOI 10.1016/j.tet.2009.12.018
Makale Linki http://dx.doi.org/10.1016/j.tet.2009.12.018
Özet
Manganese(III) acetate (Mn(OAc)3)-mediated synthesis of biaryls and heterobiaryls starting from arylboronic acid was developed under microwave irradiation in high yields. Microwaves were also used for the synthesis of Mn(OAc)3 from KMnO4 and acetic acid. Additional irradiation of this in situ generated Mn(OAc)3 with arylboronic acids, which in turn furnished the biaryls in high yields in a one pot reaction. This is superior from the point of view of yield, short reaction time, sensitive functional group toleration, and more environmentally friendly than the reported methods with a minimum amount of benzene and thiophene as a reagent but not as a solvent.
Anahtar Kelimeler
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Google Scholar 49
Scopus 3
Web of Science 32
Manganese(III) acetate-mediated synthesis of biaryls under microwave irradiation

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