| Yazarlar |
Saliha Alyar
|
Prof. Dr. Neslihan ÖZBEK
Ahi Evran Üniversitesi, Türkiye |
|
Sema Yıldırım
Erciyes Üniversitesi, Türkiye |
|
Semra İde
Hacettepe Üniversitesi, Türkiye |
|
Ray Butcher
|
| Özet |
| 2,2′-[(1E,2E)-hydrazine-1,2-diylidenedi(1E)eth-1-yl-1-ylidene] diphenol and its dimeric, binuclear Ni(II), Pd(II) and Pt(II) metal complexes were synthesized. Hydrazine derivative and its complexes were characterized by elemental analyses, LC-MS, IR, electronic spectra, 1H and 13C NMR spectra, conductivity and magnetic measurements. 1H and 13C shielding tensors for crystal structure were calculated with GIAO/DFT/B3LYP/6-311++G(d,p) methods in CDCl3. The vibrational band assignments were performed at B3LYP/6-311++G(d,p) theory level combined with scaled quantum mechanics force field (SQMFF) methodology. The antibacterial activities of synthesized compounds were studied against some Gram-positive and Gram-negative bacteria by using the microdilution and disk diffusion method. As the antibacterial activity results evidently show, the compound possessed a broad spectrum of activity against the tested bacteria. © 2014 Elsevier Ltd. All rights reserved. |
| Anahtar Kelimeler |
| Antibacterial activity | Complex | HOMO | Hydrazine | LUMO | X-ray |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY |
| Dergi ISSN | 1386-1425 |
| Dergi Tarandığı Indeksler | SCI |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2014 |
| Cilt No | 130 |
| Sayı | 1 |
| Sayfalar | 198 / 207 |
| Doi Numarası | 10.1016/j.saa.2014.03.034 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S1386142514004454 |
| Atıf Sayıları | |
| WoS | 5 |
| SCOPUS | 6 |
| Google Scholar | 8 |
