| Yazarlar |
Hamit Alyar
Çankırı Karatekin Üniversitesi, Türkiye |
|
Saliha Alyar
|
|
Arslan Ünal
Bilecik Şeyh Edebali Üniversitesi, Türkiye |
Neslihan ÖZBEK
Ahi Evran Üniversitesi, Türkiye |
|
Nurcan Karacan
Gazi Üniversitesi, Türkiye |
| Özet |
| M-toluenesulfonamide, N,N′-1,2-ethanediylbis (a disulfonamide compound, mtsen) and [Cu(II)(phenanthroline)2]mtsen compounds were newly synthesized. The molecular structure of mtsen was investigated by using elemental analyses, liquid chromatography-mass spectrometry (LC-MS), X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), dispersive Raman spectroscopy, 1H, 13C, heteronuclear chemical-shift correlation (HETCOR) and correlation spectroscopy (COSY) NMR spectroscopies. The FT-IR, dispersive Raman and far-infrared spectra of mtsen were recorded at room-temperature and discussed assisted with B3LYP/6-311G(d,p) level of theory along with scaled quantum mechanics force field (SQM-FF) method. Furthermore, 1H and 13C NMR analyses were performed at B3LYP/6-311++G(d,p) theory level using gauge including atomic orbital (GIAO) method and compared with the experimental findings. Further analyses were also made for [Cu(II)(phenanthroline)2]mtsen complex by using elemental analysis, LC-MS, magnetic susceptibility; conductivity measurement and FT-IR. The antibacterial activities of synthesized compounds were studied against some Gram-positive and Gram-negative bacteria by using the microdilution and disk diffusion method. The biological activity screening showed that complex have more activity than ligand against the tested bacteria. © 2012 Elsevier B.V. All rights reserved. |
| Anahtar Kelimeler |
| Antibacterial activity | DFT | Disulfonamides | FT-IR and Raman | SQM-FF | X-ray |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | JOURNAL OF MOLECULAR STRUCTURE |
| Dergi ISSN | 0022-2860 |
| Dergi Tarandığı Indeksler | SCI |
| Makale Dili | İngilizce |
| Basım Tarihi | 11-2012 |
| Cilt No | 1028 |
| Sayı | 1 |
| Sayfalar | 116 / 125 |
| Doi Numarası | 10.1016/j.molstruc.2012.06.046 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0022286012006060 |
| Atıf Sayıları | |
| WoS | 23 |
| SCOPUS | 26 |
| Google Scholar | 33 |
