Biologically active Schiff bases containing thiophene furan ring andtheir copper II complexes Synthesis spectral nonlinear optical and density functional studies
Yazarlar (5)
Ayla Balaban Gündüzalp Gazi Üniversitesi, Türkiye
İffet Özsen
Gazi Üniversitesi, Türkiye
Gazi Üniversitesi, Türkiye
Hamit Alyar Çankiri Karatekin Üniversitesi, Türkiye
Saliha Alyar Çankiri Karatekin Üniversitesi, Türkiye
Prof. Dr. Neslihan ÖZBEK Kırşehir Ahi Evran Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure | ||
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2016 |
| Cilt / Sayı / Sayfa | 1120 / 1 / 259–266 | DOI | 10.1016/j.molstruc.2016.05.002 |
| Özet |
| Schiff bases; 1,8-bis(thiophene-2-carboxaldimine)-p-menthane (L1) and 1,8-bis(furan-2-carboxaldimine)-p-menthane (L2) have been synthesized and characterized by elemental analysis, 1Hsingle bond13C NMR, UV–vis, FT-IR and LC-MS methods. 1H and 13C shielding tensors for L1 and L2 were calculated with GIAO/DFT/B3LYP/6-311++G(d,p) methods in CDCl3. The vibrational band assignments, nonlinear optical (NLO) activities, frontier molecular orbitals (FMOs) and absorption spectrum have been investigated by the same basis set. Schiff base-copper(II) complexes have been synthesized and structurally characterized with spectroscopic methods, magnetic and conductivity measurements. The spectroscopic data suggest that Schiff base ligands coordinate through azomethine-N and thiophene-S/furan-O donors (as SNNS and ONNO chelating systems) to give a tetragonal geometry around the copper(II … |
| Anahtar Kelimeler |
| Antibacterial activity | DFT method | NLO | Schiff base | Thiophene/furan aldehyde |
Science Direct
Biologically active Schiff bases containing thiophene furan ring andtheir copper II complexes Synthesis spectral nonlinear optical and density functional studies
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 49 |
| SCOPUS | 50 |
| Google Scholar | 59 |