New Bioactive Silver(I) Complexes: Synthesis, Characterization, Anticancer, Antibacterial and Anticarbonic Anhydrase II Activities
   
Yazarlar (5)
Ummuhan O. Ozdemir
Gazi Üniversitesi, Türkiye
Prof. Dr. Neslihan ÖZBEK Kırşehir Ahi Evran Üniversitesi, Türkiye
Zuhal Karagoz Genc Adiyaman Üniversitesi, Türkiye
Firdevs İlbiz
Gazi Üniversitesi, Türkiye
Ayla Balaban Gündüzalp Gazi Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure
Dergi ISSN 0022-2860 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 06-2017
Cilt / Sayı / Sayfa 1138 / 1 / 55–63 DOI 10.1016/j.molstruc.2017.02.101
Özet
Silver(I) complexes of alkyl sulfonic acide hydrazides were newly synthesized as homologous series. Methanesulfonic acide hydrazide (L1), ethanesulfonic acide hydrazide (L2), propanesulfonic acide hydrazide (L3) and butanesulfonic acide hydrazide (L4) were used for complexation with Ag(I) ions. The silver complexes obtained in the mol ratio of 1:2 have the structural formula as Ag(L1)2NO3 (I), Ag(L2)2NO3 (II), Ag(L3)2NO3 (III), (Ag(L4)2NO3 (IV). The Ag(I) complexes exhibit distorted linear two-fold coordination in [AgL2]+ cations with uncoordinated nitrates. Ligands are chelated with silver(I) ions through unsubstituted primary nitrogen in hydrazide group. Ag(I) complexes were characterized by using elemental analysis, spectroscopic methods (FT-IR, LC-MS), magnetic susceptibility and conductivity measurements. Silver(I) complexes were optimized using PBEPBE/LanL2DZ/DEF2SV basic set performed by …
Anahtar Kelimeler
Alkyl sulfonic acide hydrazide | Anti carbonic anhydrase II | Antibacterial | Anticancer | Silver(I) complexes