| Yazarlar |
Süheyla Özbey
Hacettepe Üniversitesi, Türkiye |
|
Filiz Betül Kaynak
Hacettepe Üniversitesi, Türkiye |
|
Toğrul Mahmut
|
Prof. Dr. Nadir DEMİREL
Dicle Üniversitesi, Türkiye |
|
Halil Hoşgören
Dicle Üniversitesi, Türkiye |
| Özet |
| A new complex of a chiral monoaza-crown ether, [R-(-)-2-ethyl-N-benzyl-4,7, 10,13-tetraoxa-8,9-benzo-1-azacyclopentadec-8-ene-NaClO4], has been prepared and studied by x-ray diffraction. The compound crystallizes in space group P21 with cell dimensions a = 8.721(1), b = 16.318(2), c = 8.905(1) Å, β = 100.80(1)°. The sodium cation is heptacoordinated and located significantly out of the best plane of the macrocycle ring. The donor atoms of the macrocycle are in the half-chair arrangement. |
| Anahtar Kelimeler |
| Benzo-monoaza-15-crown-5 | Chiral crown ether | Crystal structure | Sodium complex |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | J. Of Inclusion Phenomena And Macrocyclic Chemistry |
| Dergi ISSN | 1573-1111 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2003 |
| Cilt No | 45 |
| Sayı | 45 |
| Sayfalar | 123 / 128 |
