Crystal Structure Of An İnclusion Complex Between Chiral Monoaza 15 Crown 5 And S 1 Phenyl Ethyl Ammonium Percholorate
Yazarlar (5)
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Zeitschrift Fur Kristallographie | ||
| Dergi ISSN | 0044-2968 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2003 |
| Kabul Tarihi | 12-04-2026 | Yayınlanma Tarihi | – |
| Cilt / Sayı / Sayfa | 218 / 5 / 381–384 | DOI | 10.1524/zkri.218.5.381.20734 |
| Özet |
| A new type of inclusion complex, S(–)-1 phenyl ethyl ammonium percholorate complex of R-(–)-2-ethyl - N - benzyl - 4, 7, 10, 13 - tetraoxa -1- azacyclopentadecane, has been prepared and studied by NMR, IR and single crystal X-ray diffraction techniques. The compound crystallizes in space group P21 with cell dimensions a = 10.0000(8), b = 12.281(2), c = 12.331(1)Å, β = 102.052(7), Z = 2 The host-guest complex is held together by a strong system of hydrogen bonds between the two protons of the ammonium ion as well as the nitrogen and four oxygen atoms of the crown ether The C—O and C—C distances of the 15-membered ring average 1.418 and 1.501 Å while the O—C—C and C—O—C angles average 110.2 and 113.3°. The average N—C distance is 1.476 Å. |
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| Google Scholar | 2 |
| Web of Science | 8 |