| Yazarlar |
İbrahim Işıldak
Yıldız Teknik Üniversitesi, Türkiye |
|
Murat Yolcu
Giresun Üniversitesi, Türkiye |
|
Ömer Işıldak
Gaziosmanpaşa Üniversitesi, Türkiye |
Nadir DEMİREL
Dicle Üniversitesi, Türkiye |
|
Giray Topal
Dicle Üniversitesi, Türkiye |
|
Halil Hoşgören
Dicle Üniversitesi, Türkiye |
| Özet |
| Two diaza-crown ether compounds were synthesized and evaluated as Ag +-selective carriers in polyvinylchloride (PVC) membrane electrodes of solid-state type. The all-solid-state PVC membrane electrode based on N,N-Dibenzyl-dibenzo-diaza-18-crown-6 exhibited a super-Nernstian response (75±10∈mV per decade) over the concentration range of 1×10-1 to 7×10-6∈M of Ag+ ion and a detection limit of 3×10-6∈M, at a wide range of pH (pH 4-7). The response time of the electrode was fast (less than ∼10s), and it can be used for three months without any significant deviation in potential. The proposed all-solid-state PVC membrane electrodes revealed high selectivity toward Ag+ ion with respect to alkali, alkaline earth, heavy and transition metal ions. A flow-through cell of all-solid-state PVC membrane Ag+-selective electrode based on N,N-Dibenzyl-dibenzo-diaza-18-crown- 6 has also been prepared and applied for flow-injection analysis of Ag + ion in solution. © Springer-Verlag 2003. |
| Anahtar Kelimeler |
| All-solid-state | Diaza-crown ethers | FIA | PVC membrane | Silver-selective electrodes |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | Microchimica Acta |
| Dergi ISSN | 0026-3672 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2004 |
| Cilt No | 144 |
| Sayı | 1 |
| Sayfalar | 177 / 181 |
| Doi Numarası | 10.1007/s00604-003-0072-7 |
| Atıf Sayıları | |
| SCOPUS | 26 |
| Google Scholar | 43 |
