Yazarlar |
Prof. Dr. Nadir DEMİREL
Dicle Üniversitesi, Türkiye |
Yasemin Bulut
Dicle Üniversitesi, Türkiye |
Halil Hoşgören
Dicle Üniversitesi, Türkiye |
Özet |
Complexation of amino acids as their sodium and potassium salts by optically active diaza crown ethers has been investigated in transport across bulk liquid membranes containing the carriers and in extraction experiments. The observed enantioselectivity was achieved by (noncovalent) steric and repulsive interactions between the side arm of the crown ether and functional group(s) of the amino acids. The highest enantioselectivity was observed in the case of tryptophan. © 2004 Wiley-Liss, Inc. |
Anahtar Kelimeler |
Crown compounds | Host-guest systems | Molecular recognition | Supramolecular chemistry | Transport of amino acids |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | Chirality |
Dergi ISSN | 0899-0042 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 01-2004 |
Cilt No | 16 |
Sayı | 16 |
Sayfalar | 347 / 350 |
Doi Numarası | 10.1002/chir.20046 |