| Yazarlar (5) |
Toğrul Mahmut
|
Prof. Dr. Nadir DEMİREL
Dicle Üniversitesi, Türkiye |
|
Filiz Betül Kaynak
Hacettepe Üniversitesi, Türkiye |
|
Süheyla Özbey
Hacettepe Üniversitesi, Türkiye |
|
Halil Hoşgören
Dicle Üniversitesi, Türkiye |
| Özet |
| The X-ray crystal structure of IX, perchlorate salt of R-(−-2-ethyl-N-benzyl-4,7,19,13-tetraoxa-8,9-benzo-1-azacyclopentadec-8-ene has been determined. In the molecule, the protonated nitrogen atom participates in two N-H⋯O hydrogen bonds. The unusually high proton affinity of aza crown ether leads to the formation of diastreomer instead of complex formation with chiral R-(+)-1-phenyl ethyl ammonium perchlorate and S-(−)-1-phenyl ethyl ammonium perchlorate. The complex ability of host ethers was evaluated in terms of structural modification. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | J. Of Inclusion Phenomena And Macrocyclic Chemistry |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2004 |
| Cilt No | 50 |
| Sayı | 50 |
| Sayfalar | 165 / 171 |
