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Synthesis of novel chiral C 2 symmetric diaza 18 crown 6 ether derivatives and their enantioselective recognition of amino acid derivatives    
Yazarlar
Yılmaz Turgut
Dicle Üniversitesi, Türkiye
Prof. Dr. Nadir DEMİREL Prof. Dr. Nadir DEMİREL
Dicle Üniversitesi, Türkiye
Halil Hoşgören
Dicle Üniversitesi, Türkiye
Özet
New chiral diaza-18-crown-6 ether derivatives, 5 and 6 were synthesized from (R)-(-)-2-amino-1-bütanol. These chiral artificial receptors exhibit pronounced chiral recognition toward the enantiomers of L- and D- amino acid derivatives. The highest enantioselectivity was observed in the case of Trp-OMe·HCl (KD/KL = 12.5). © Springer 2006.
Anahtar Kelimeler
Amino acid | Chiral aza crown ether | Complexation | Molecular recognition
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı J. of Inclusion Phenomena and Macrocyclic Chemistry
Dergi ISSN 0923-0750
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2006
Cilt No 54
Sayı 54
Sayfalar 29 / 33
Doi Numarası 10.1007/s10847-005-3125-1