Synthesis of novel chiral C 2 symmetric diaza 18 crown 6 ether derivatives and their enantioselective recognition of amino acid derivatives
    
Yazarlar (3)
Yılmaz Turgut
Dicle Üniversitesi, Türkiye
Prof. Dr. Nadir DEMİREL Dicle Üniversitesi, Türkiye
Halil Hoşgören
Dicle Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Inclusion Phenomena
Dergi ISSN 0923-0750
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2006
Cilt / Sayı / Sayfa 54 / 1 / 29–33 DOI 10.1007/s10847-005-3125-1
Özet
New chiral diaza-18-crown-6 ether derivatives, 5 and 6 were synthesized from (R)-(-)-2-amino-1-bütanol. These chiral artificial receptors exhibit pronounced chiral recognition toward the enantiomers of L- and D- amino acid derivatives. The highest enantioselectivity was observed in the case of Trp-OMe·HCl (KD/KL = 12.5). © Springer 2006.
Anahtar Kelimeler
Amino acid | Chiral aza crown ether | Complexation | Molecular recognition