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Solvent free Synthesis of Ferrocene Based Chiral Schiff base Ligands Under Microwave Irradiation and Application to Enantioselective nitro aldol Henry Reaction   
Yazarlar (3)
Gülşen Öztürk
Dicle Üniversitesi, Türkiye
Mehmet Çolak
Dicle Üniversitesi, Türkiye
Prof. Dr. Nadir DEMİREL Prof. Dr. Nadir DEMİREL
Kırşehir Ahi Evran Üniversitesi, Türkiye
Devamını Göster
Özet
Chiral Schiff‐bases 3a, 3b, 3c, 3d, 3e, 3f based on ferrocene were designed and synthesized using solvent‐free methods by mixing ferrocene carbaldehyde 1 with amino alcohols and amines 2a, 2b, 2c, 2d, 2e, 2f under microwave irradiation and classical method for the enantioselective nitroaldol (Henry) reaction. The Schiff‐bases were obtained in shorter reaction times and improved yield under microwave irradiation method over classical method. The highest enantioselectivity was observed in ligand 3e (95% ee) when CH2Cl2 was used as solvent. Chirality, 2011. © 2011 Wiley‐Liss, Inc.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Chirality
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2011
Cilt No 23
Sayı 5
Sayfalar 374 / 378
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Google Scholar 6

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