Synthesis, structural characterization, Hirshfeld analyses, and biological activity studies of Ni(II) and Zn(II) complexes containing the sulfonohydrazone group
Yazarlar (6)
Doç. Dr. Murat ÇINARLI Kırşehir Ahi Evran Üniversitesi, Türkiye
Çiğdem Yüksektepe Ataol Çankırı Karatekin Üniversitesi, Türkiye
Hümeyra Batı
Ondokuz Mayıs Üniversitesi, Türkiye
Feyizan Güntepe
Ondokuz Mayis Üniversitesi
Prof. Dr. Hatice ÖĞÜTCÜ Kırşehir Ahi Evran Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayıs Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Inorganica Chimica Acta (Q2)
Dergi ISSN 0020-1693 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2019
Kabul Tarihi 12-04-2026 Yayınlanma Tarihi
Cilt / Sayı / Sayfa 484 / 1 / 87–94 DOI 10.1016/j.ica.2018.09.027
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0020169318308491
Özet
In this work, the nickel ([NiL2]) and zinc ([ZnL2]) complex structures of N'-(dipyridin-2-ylmethylene)-4-methylbenzenesulfonohydrazide [LH] have been synthesized. The structures of the complexes have been investigated by using X-ray single crystal, elemental analysis, FTIR, and UV–Vis spectrophotometric methods. The two compounds crystallize isotypic in monoclinic space group P21/c. From elemental analysis data, the stoichiometry of the complexes was found to be 1:2 (metal/ligand). IR spectra indicate that the ligand behaves as tridentate with an NNO donor sequence in its enolate form. The coordination of the metal atoms takes place through the pyridine nitrogen, imine nitrogen, and sulfonyl oxygen atoms. Thermal analysis of [NiL2] and [ZnL2] complexes were performed and the thermoanalytical curves obtained. Hirshfeld surfaces of [NiL2] and [ZnL2] complexes were investigated and the interaction …
Anahtar Kelimeler
Antimicrobial activity | Hirshfeld surface | Metal complex | Pathogenic microorganism | Single crystal | Sulfonohydrazone