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Adsorption of basic dye from aqueous solutions by modified sepiolite Equilibrium kinetics and thermodynamics study   
Yazarlar (3)
Erdal Eren
Bilecik Şeyh Edebali Üniversitesi, Türkiye
Bilge Eren
Bilecik Şeyh Edebali Üniversitesi, Türkiye
Prof. Dr. Harun ÇİFTÇİ Prof. Dr. Harun ÇİFTÇİ
Ahi Evran Üniversitesi, Türkiye
Devamını Göster
Özet
The adsorption behavior of crystal violet (CV+) from aqueous solution onto a manganese oxide-coated (MCS) sepiolite sample was investigated as a function of parameters such as initial CV+ concentration, contact time and temperature. The Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms. The Langmuir monolayer adsorption capacity of MCS was estimated as 319 mg/g. The pseudo-first-order. pseudo-second-order kinetic and the intraparticle diffusion models were used to describe the kinetic data and rate constants were evaluated. The values of the energy (E-a), enthalpy (Delta H-not equal) and entropy of activation (Delta S-not equal) were 56.45 kJ/mol, 53.90 kJ/mol and - 117.26J/(mol K), respectively, at pH 6.5. The quite high adsorption capacity and high adsorption rate of MCS will provide an important advantage for use of this material in basic dye solutions. (C) 2009 Elsevier B.V. All rights reserved.
Anahtar Kelimeler
Dye adsorption | Clay | Kinetic | Sepiolite | X-ray diffraction
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Desalination
Dergi ISSN 0011-9164
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 03-2010
Cilt No 252
Sayı 1
Sayfalar 88 / 96
Doi Numarası 10.1016/j.desal.2009.10.020
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0011916409012417