Optimization of Analytical Parameters for Determination of Iron Nickeland Cobalt in Plants with RP HPLC
Yazarlar (4)
Prof. Dr. Harun ÇİFTÇİ Kırşehir Ahi Evran Üniversitesi, Türkiye
Ali Ölçücü Fırat Üniversitesi, Türkiye
Ahmet Özkaya Adıyaman Üniversitesi, Türkiye
Tacettin Çiftçi Kırşehir Ahi Evran Üniversitesi
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | ASIAN JOURNAL OF CHEMISTRY (Q4) | ||
| Dergi ISSN | 0970-7077 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2009 |
| Kabul Tarihi | 12-04-2026 | Yayınlanma Tarihi | – |
| Cilt / Sayı / Sayfa | 21 / 4 / 2643–2652 | DOI | – |
| Özet |
| This study optimized the analytical parameters such as combination of mobile phase, pH of mobile phase, attempt effect of strange ions and current rate for simultaneous determination of iron, nickel and cobalt. 4-(2-Pyridiylazo) resorcinol (PAR) ligand is used for metal chelates. The metal-PAR chelates were separated on a Luna C18 siloxane bonded phase and eluted within 7.4 min of Co-PAR, 9.6 min of Fe-PAR and 12.4 min of Ni-PAR with methanol-water-acetonitrile-(1 Ũ 10-2 mol L-1) sodium acetate (55: 40: 2.5: 2.5 v/v)(pH 5.3). Detection limits of process for Fe-PAR, Ni-PAR and Co-PAR under optimized conditions (500 nm) were found as 4.45, 3.26 and 1.86 ĩg L-1, respectively. The analysis of Fe, Ni and Co ions in plant samples under optimized conditions were carried out by HPLC. |
| Anahtar Kelimeler |
| 4-(2-Pyridylazo) resorcinol | Cobalt | HPLC | Iron | Nickel | Trace element | UV-Visible |
