Determination of cobalt in some plants by reversed phase highperformance liquid chromatography
Yazarlar (1)
Prof. Dr. Harun ÇİFTÇİ
Firat Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Asian Journal of Chemistry | ||
| Dergi ISSN | 0970-7077 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2008 |
| Cilt / Sayı / Sayfa | 20 / 4 / 3025–3032 | DOI | – |
| Özet |
| The separation and determination of cobalt chelate with 4-(2-pyridylazo)resorcinol (PAR) by reversed-phase HPLC was investigated. The Co(III)-PAR chelate was separated on a C,x siloxane bonded phase and eluted within 5.4 min with methanol-water-acetonitrile (1 x 10(-2) mol L-1) and sodium acetate (55:40:2.5:2.5 v/v) containing 5 x 10(-3) mol L-1 ethylenedi-aminetatraacetic acid (EDTA) (pH 7.5). The detection limits of Co(III) at 520 nm are 1.2 mu g L-1. The method was applied to the determination of cobalt in some samples of plants. The contents of cobalt in the plants samples were found in the ranges, 0.941-0.141 mg/kg (dry matter). Rosa canina is rather rich in cobalt and is recommended as a source. |
| Anahtar Kelimeler |
| HPLC | 4-(2-pyridylazo)resorcinol | UV-Visible | cobalt | PAR | resorcinol | Rosa canina |
