Yazarlar (1) |
Prof. Dr. Harun ÇİFTÇİ
Kırşehir Ahi Evran Üniversitesi, Türkiye |
Özet |
The separation and determination of cobalt chelate with 4-(2-pyridylazo)resorcinol (PAR) by reversed-phase HPLC was investigated. The Co(III)-PAR chelate was separated on a C,x siloxane bonded phase and eluted within 5.4 min with methanol-water-acetonitrile (1 x 10(-2) mol L-1) and sodium acetate (55:40:2.5:2.5 v/v) containing 5 x 10(-3) mol L-1 ethylenedi-aminetatraacetic acid (EDTA) (pH 7.5). The detection limits of Co(III) at 520 nm are 1.2 mu g L-1. The method was applied to the determination of cobalt in some samples of plants. The contents of cobalt in the plants samples were found in the ranges, 0.941-0.141 mg/kg (dry matter). Rosa canina is rather rich in cobalt and is recommended as a source. |
Anahtar Kelimeler |
HPLC | 4-(2-pyridylazo)resorcinol | UV-Visible | cobalt | PAR | resorcinol | Rosa canina |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ASIAN JOURNAL OF CHEMISTRY |
Dergi ISSN | 0970-7077 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 01-2008 |
Cilt No | 20 |
Sayı | 4 |
Sayfalar | 3025 / 3032 |