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Determination of cobalt in some plants by reversed phase highperformance liquid chromatography   
Yazarlar (1)
Prof. Dr. Harun ÇİFTÇİ Prof. Dr. Harun ÇİFTÇİ
Kırşehir Ahi Evran Üniversitesi, Türkiye
Devamını Göster
Özet
The separation and determination of cobalt chelate with 4-(2-pyridylazo)resorcinol (PAR) by reversed-phase HPLC was investigated. The Co(III)-PAR chelate was separated on a C,x siloxane bonded phase and eluted within 5.4 min with methanol-water-acetonitrile (1 x 10(-2) mol L-1) and sodium acetate (55:40:2.5:2.5 v/v) containing 5 x 10(-3) mol L-1 ethylenedi-aminetatraacetic acid (EDTA) (pH 7.5). The detection limits of Co(III) at 520 nm are 1.2 mu g L-1. The method was applied to the determination of cobalt in some samples of plants. The contents of cobalt in the plants samples were found in the ranges, 0.941-0.141 mg/kg (dry matter). Rosa canina is rather rich in cobalt and is recommended as a source.
Anahtar Kelimeler
HPLC | 4-(2-pyridylazo)resorcinol | UV-Visible | cobalt | PAR | resorcinol | Rosa canina
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ASIAN JOURNAL OF CHEMISTRY
Dergi ISSN 0970-7077
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2008
Cilt No 20
Sayı 4
Sayfalar 3025 / 3032
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
WoS 7

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