| Yazarlar (3) |
Muhammet Şakir Eren
|
|
Hasan Arslanoğlu
Kırşehir Ahi Evran Üniversitesi, Türkiye |
Prof. Dr. Harun ÇİFTÇİ
Kırşehir Ahi Evran Üniversitesi, Türkiye |
| Özet |
| Cellulosic woven waste was used as a biomass material to prepare a Cu-doped BTC (Cu-BTC) adsorbent, which was then used to remove methylene blue (Basic Blue 9) from wastewater. Cellulosic woven waste was used as a biomass material to prepare a Cu-doped BTC (Cu-BTC) adsorbent, which was then used to remove methylene blue (Basic Blue 9) from wastewater. The Cu-BTC had higher adsorption capacity for methylene blue (BB9) than pure woven waste because it had high specific surface area and electrostatic interaction with cationic methylene blue molecules. The Cu-BTC removed methylene blue from wastewater rapidly and effectively and had an excellent adsorption capacity (197.90 mg/g). In batch process, the adsorption efficiency of the adsorbent for removal of BB9 was evaluated within 20 degrees C-60 degrees C, with initial BB9 concentrations of 50 - 200 mg/L and initial pH of 2 -11. The Cu-BTC activation tailored the topological and textural properties of the obtained adsorbent, leading to a relatively large surface area of 1418.3 m(2)/g and pores with a volume of 0.491 cm(3)/g and an average size of 2.11 nm. The adsorption process fitted well with the Langmuir isotherm and the pseudo-second-order kinetic model. The possible mechanism for methylene blue removal mainly involved electrostatic attraction and micro pores. This study can serve as a guide for value-added utilization of cellulosic woven waste and as a practical method for the removal of methylene blue from wastewater. Adsorption of methylene blue onto the CuBTC is an effective and eco-friendly method for its removal from wastewater. |
| Anahtar Kelimeler |
| Cellulosic woven waste | Metal-organic framework MOF | Methylene blue (Basic Blue 9) removal | Adsorption | Desorption | Isotherm-kinetic-thermod namic |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | Journal of Environmental Chemical Engineering |
| Dergi ISSN | 2213-2929 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 10-2020 |
| Cilt No | 8 |
| Sayı | 5 |
| Sayfalar | 1 / 11 |
| Doi Numarası | 10.1016/j.jece.2020.104247 |
| Atıf Sayıları | |
| WoS | 59 |
